96

This number is a composite.

The smallest integer n for which π(n) = n/4. [Woods]

The only double-digit number that can be expressed as sum of two distinct primes, each ending with the digit 3, in the largest number n of different ways, (case n=3), i.e., 96 = 13 + 83 = 23 + 73 = 43 + 53. [Loungrides]

Every integer greater than 96 may be represented as a sum of distinct super-prime numbers.